If you're new to Perl, you should start with perlintro, which is a general intro for beginners and provides some background to help you navigate the rest of Perl's extensive documentation.
Overview
perl Perl overview (this section)
perlintro Perl introduction for beginners
perltoc Perl documentation table of contents
Tutorials
perlreftut Perl references short introduction
perldsc Perl data structures intro
perllol Perl data structures: arrays of arrays
perlrequick Perl regular expressions quick start
perlretut Perl regular expressions tutorial
perlboot Perl OO tutorial for beginners
perltoot Perl OO tutorial, part 1
perltooc Perl OO tutorial, part 2
perlbot Perl OO tricks and examples
perlperf Perl Performance and Optimization Techniques
perlstyle Perl style guide
perlcheat Perl cheat sheet
perltrap Perl traps for the unwary
perldebtut Perl debugging tutorial
perlfaq Perl frequently asked questions
perlfaq1 General Questions About Perl
perlfaq2 Obtaining and Learning about Perl
perlfaq3 Programming Tools
perlfaq4 Data Manipulation
perlfaq5 Files and Formats
perlfaq6 Regexes
perlfaq7 Perl Language Issues
perlfaq8 System Interaction
perlfaq9 Networking
Reference Manual
perlsyn Perl syntax
perldata Perl data structures
perlop Perl operators and precedence
perlsub Perl subroutines
perlfunc Perl built-in functions
perlopentut Perl open() tutorial
perlpacktut Perl pack() and unpack() tutorial
perlpod Perl plain old documentation
perlpodspec Perl plain old documentation format specification
perlrun Perl execution and options
perldiag Perl diagnostic messages
perllexwarn Perl warnings and their control
perldebug Perl debugging
perlvar Perl predefined variables